微波消解-电感耦合等离子体质谱法测定海泡石中的稀土元素   总被引：3，自引：3，他引：0  

张楠  徐铁民  吴良英  魏双  方蓬达  王家松 《岩矿测试》2018,37(6):644-649

海泡石是一种纤维状含水的富镁硅酸盐黏土矿,其中的稀土元素含量在1×10~(-7)～1×10~(-5)之间,目前还没有建立海泡石中稀土元素的国家标准分析方法。测定岩石中的稀土元素主要是采用电感耦合等离子体质谱法(ICP-MS),样品前处理一般采用封闭溶矿和碱熔,但这两种处理方法耗时较长,效率不高。本文通过比较硝酸-氢氟酸-过氧化氢、硝酸-氢氟酸、硝酸-过氧化氢三种样品前处理方法,确定使用硝酸-氢氟酸溶矿,然后进行微波消解同时赶去氢氟酸,避免氢氟酸与稀土元素生成难溶的氟化物,再采用ICP-MS法测定15种稀土元素的含量。由于海泡石中的镁含量较高,为降低基体效应,以~(103)Rh和~(185)Re作内标补偿基体效应和校正灵敏度漂移,各元素测定值的准确性显著提高,回收率为91. 2%～110. 9%,检出限为0. 002～0. 011μg/L,精密度≤2. 79%。本方法与封闭酸溶ICP-MS法的分析结果吻合较好,且用酸量少(7 mL),溶矿效率高(1 h),检出限更低。  相似文献   

基于多源数据的湘北地区春季一次冰雹过程的观测分析          下载免费PDF全文

朱家亮  潘江萍  邱丽静  吕渊 《中低纬山地气象》2022,46(2):46-54

新型探测资料在强对流短临预报中发挥着重要作用.该文以2020年3月22日湘北地区春季一次冰雹过程为研究对象,运用多普勒天气雷达、风廓线雷达和地基微波辐射计等新型探测资料对该过程观测分析。结果表明：①此次过程发生在冷空气南下与南支槽前暖湿空气交汇背景下,受中低层切变线与急流影响,冰雹风暴生成前回暖明显,环境垂直风切变大;风暴由地面辐合线触发产生。②此次超级单体降雹过程在雷达回波中表现出“三体散射”、“V型缺口”、中气旋等特征;VIL、低仰角大风速核对冰雹、大风预警有很好的指示。③风廓线雷达探测到,风暴影响前超低空急流加强,中层有干侵入,低层垂直速度出现波动,风暴临近时超低空急流减弱。④地基微波辐射计监测发现,风暴影响前高空湿度增大,K指数、TT指数呈同趋势变化,而K指数预警灵敏度高于TT指数;风暴影响阶段,高空温度、相对湿度和大气不稳定指数出现不同程度跃升和突降。  相似文献   

All-sky Data Assimilation of MWTS-2 and MWHS-2 in the Met Office Global NWP System.     

Fabien CARMINATI  Stefano MIGLIORINI 《大气科学进展》2021,38(10):1682-1694

Microwave radiances from passive polar-orbiting radiometers have been, until recently, assimilated in the Met Office global numerical weather prediction system after the scenes significantly affected by atmospheric scattering are discarded.Recent system upgrades have seen the introduction of a scattering-permitting observation operator and the development of a variable observation error using both liquid and ice water paths as proxies of scattering-induced bias. Applied to the Fengyun 3 Microwave Temperature Sounder 2(MWTS-2) and the Microwave Humidity Sounder 2(MWHS-2), this methodology increases the data usage by up to 8% at 183 GHz. It also allows for the investigation into the assimilation of MWHS-2 118 GHz channels, sensitive to temperature and lower tropospheric humidity, but whose large sensitivity to ice cloud have prevented their use thus far. While the impact on the forecast is mostly neutral with small but significant shortrange improvements, 0.3% in terms of root mean square error, for southern winds and low-level temperature, balanced by 0.2% degradations of short-range northern and tropical low-level temperature, benefits are observed in the background fit of independent instruments used in the system. The lower tropospheric temperature sounding Infrared Atmospheric Sounding Interferometer(IASI) channels see a reduction of the standard deviation in the background departure of up to 1.2%. The Advanced Microwave Sounding Unit A(AMSU-A) stratospheric sounding channels improve by up to 0.5% and the Microwave Humidity Sounder(MHS) humidity sounding channels improve by up to 0.4%.  相似文献   

基于机载微波辐射计探测大气水汽通道饱和问题研究     

王婉  雷恒池  聂皓浩  王兆宇  郭晓军 《气象学报》2021,79(3):509-520

183.31 GHz微波辐射计在探测低含量水汽时具有优势,但也存在通道饱和问题,定量研究该问题对明确该类型仪器探测水汽能力和适用范围具有重要意义。基于天津市人工影响天气办公室增雨飞机运-12搭载的183.31 GHz微波辐射计GVR（G-band water Vapor Radiometer）,采用探空资料对该辐射计4个通道进行饱和问题研究,定量计算其饱和阈值及探测灵敏度,分析各通道水汽探测能力及适用范围。结果表明:机载微波辐射计4个通道水汽探测灵敏度及饱和阈值与观测高度有关,当水汽含量较低时,通道1（（183±1）GHz）观测高度越高灵敏度越高,通道3（（183±7）GHz）和通道4（（183±14）GHz）观测高度越高灵敏度越低,通道2（（183±3）GHz）灵敏度几乎不受观测高度影响,通道1和通道4观测高度越高积分水汽探测饱和阈值越小,观测高度越低饱和阈值越大,通道2和通道3饱和阈值几乎不受观测高度影响。晴空条件下选择水汽探测能力最强的单通道对积分水汽含量进行反演,当积分水汽含量处于0—1.3、1.3—4.0和4.0—9.8 mm时,分别选择通道1、通道2、通道3作为反演通道,不同观测高度的积分水汽含量反演均适用。云的发射作用使辐射计各通道亮温升高,亮温升高幅度与云液态水含量、云与观测高度的距离及云厚有关,云液态水含量越大,各通道水汽探测灵敏度及饱和阈值越小;云天条件下选择水汽探测能力最强的双通道对积分水汽含量进行反演,以液态水路径区间来选择合适的水汽探测通道,液态水含量越高,积分水汽可探测范围越小。要探测到0.1 mm的积分水汽含量变化,机载微波辐射计（GVR）在晴空条件下的水汽探测适用范围为0—9.8 mm,其探测能力在云天条件下减弱,水汽探测适用范围因云液态水含量不同而不同。   相似文献   

微波辐射计在对流天气预报中的应用     

蔡奕萍  袁志扬  李婵珠  黄锋 《广东气象》2021,43(1)

选取2016—2018年每年4—9月份RPG-HATPRO型42通道微波辐射计观测的不稳定指数参数(K、SI、CAPE、LI)及水汽参数(IWV、LWP),研究得出各参数触发雷雨大风、短时强降水的阈值条件为K>37℃、SI<-1℃、IWV>60 kg/m~2、LWP>400 g/m~2,而LI、CAPE无法对3种天气类型进行区分。利用费舍判别分析方法,将不稳定指数参数及水汽参数作为预报因子,建立预报方程并进行检验,结果表明:二级判别方程预测对流天气的准确率为76%,可以作为预报对流天气的辅助工具;多级判别方程不能很好地区分3种天气类型,但将其作为修正后的二级判别方程使用,能提高对流天气的测中概率。  相似文献   

基于微波辐射计的短时强降水潜势预报     

高美谭  廖菲  周芯玉  杨慧燕  胡婷 《广东气象》2021,43(2):1-4

微波辐射计可获取高时间分辨率的大气层结信息,为探索其在短时强降水预报方面的应用潜力,利用微波辐射计仪器获得对流参数特征,提取对短时强降水敏感的对流参数作为预报因子,并利用叠套法建立短时强降水潜势预报。结果表明:液态水路径LWP、SI、LI、CAPE、KOI这5种参数可作为预报因子建立潜势预报,经验证后得出短时强降水的POD、CSI、FAR分别为53.85%、50.01%、12.49%;另外,研究利用LWP的标准偏差在短时强降水发生前明显增大的特征改进预报,POD和CSI分别提升至73.08%、63.33%,FAR虽然增加至17.39%,但增量仅有4.9%。改进后的短时强降水预报效果提升明显,这说明水汽参数LWP在短时强降水预报中有较强的指示意义。  相似文献   

微波等离子体原子发射光谱法测定偏远矿区海泡石中的主微量元素     

周学忠  谢华林 《岩矿测试》2021,(5):680-687

海泡石是具有层状结构的含水富镁硅酸盐黏土矿物,其中无机元素含量是揭示其成矿物质来源、成矿流体性质和矿床成因的重要依据,通常采用电感耦合等离子体发射光谱/质谱法(ICP-OES/MS)进行测定,等离子体(ICP)的高温激发会产生成大量谱线干扰,维持ICP稳定工作需使用高纯氩气,持续供气对于偏远矿区海泡石的检测还将面对气体采购和运输不便的问题。本文基于微波等离子体原子发射光谱(MP-AES)的低温激发技术减少光谱干扰,建立了准确测定偏远矿区海泡石中主量元素Mg、Al、Ca、Fe、K、Na和微量元素Cu、Zn、Mn、Pb含量的分析方法。利用硝酸-盐酸-氢氟酸混合酸对海泡石进行微波消解,避免了样品处理过程中分析元素的损失,加快了样品处理速度,同时提高了样品溶液的稳定性。通过选择各元素光谱线的分析波长,并利用快速线性干扰校正(FLIC)技术校正光谱干扰,以Lu为内标元素校正基体效应,提高了灵敏度和准确度。各元素的检出限为0.19～14.6μg/L。海泡石国家标准物质(GBW07138)各元素测定值与认定值的相对误差在-5.0%～6.7%之间。本方法具有检出限低、线性范围宽、结果准确等优点;MP-AES采用自带的氮气发生器为等离子体提供氮气作为工作气,无需引入复杂气体,提高了分析效率,尤其适用于气体采购和运输不便的偏远矿区。  相似文献   

微波消解-电感耦合等离子体质谱法测定土壤中稀土元素条件优化     

张祎玮  蒋俊平  李浩  沈讷敏 《岩石矿物学杂志》2021,40(3):605-613

稀土元素因其用途广泛,已经得到了越来越多的关注,被应用于各个行业。研究表明,稀土元素对作物的光合作用、产量、抗逆、品质、发育和养分吸收等具有重要作用。作物中的稀土元素主要来自对土壤中稀土元素的吸收,因此,有效分解并快速测定土壤中的稀土元素,可以合理指导稀土元素的施用,对作物的生长和土壤的营养状况具有重要作用。本文比较了敞口酸溶、密闭消解、微波消解和碱熔等4种消解样品前处理方法,最终确定采用微波消解-电感耦合等离子体质谱法(ICP-MS)快速测定土壤中的稀土元素,并通过优化微波消解的条件,选择合适的试剂用量、消解温度、消解时间,对方法的检出限、精密度、准确度、回收率进行了实验,结果显示其测定均值与标准值基本吻合,相对误差(RE)绝对值为0.16%～3.39%,精密度为0.27%～5.09%,均小于10%,加标回收率为93.1%～106.0%。该方法准确度高、稳定性好,可以有效地应用于土壤中稀土元素的分析测定。  相似文献   

Optimisation of the Population Monte Carlo algorithm: Application to constraining isocurvature models with cosmic microwave background data     

D. Moodley  K. Moodley 《Astronomische Nachrichten》2016,337(6):672-682

We optimise the parameters of the Population Monte Carlo algorithm using numerical simulations. The optimisation is based on an efficiency statistic related to the number of samples evaluated prior to convergence, and is applied to a D ‐dimensional Gaussian distribution to derive optimal scaling laws for the algorithm parameters. More complex distributions such as the banana and bimodal distributions are also studied. We apply these results to a cosmological parameter estimation problem that uses CMB anisotropy data from the WMAP nine‐year release to constrain a six parameter adiabatic model and a fifteen parameter admixture model, consisting of correlated adiabatic and isocurvature perturbations. In the case of the adiabatic model and the admixture model we find that the number of sample points increase by factors of 3 and 20, respectively, relative to the optimal Gaussian case. This is due to degeneracies in the underlying parameter space. The WMAP nine‐year data constrain the admixture model to have an isocurvature fraction of 36.3 ± 2.8 %. (© 2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

Latitudinal and Scan-dependent Biases of Microwave Humidity Sounder Measurements and Their Dependences on Cloud Ice Water Path     

Anqi CAI  Xiaolei ZOU 《大气科学进展》2019,36(5):557-569

The relationship between differences in microwave humidity sounder(MHS)–channel biases which represent measured brightness temperatures and model-simulated brightness temperatures, and cloud ice water path(IWP) as well as the influence of the cloud liquid water path(LWP) on the relationship is examined. Seven years(2011–17) of NOAA-18 MHS-derived measured brightness temperatures and IWP/LWP data generated by the NOAA Comprehensive Large Array-data Stewardship System Microwave Surface and Precipitation Products System are used. The Community Radiative Transfer Model, version2.2.4, is used to simulate model-simulated brightness temperatures using European Center for Medium-Range Weather Forecasts reanalysis data as background fields. Scan-angle deviations of the MHS window channel biases range from-1.7 K to1.0 K. The relationships between channels 2, 4, and 5 biases and scan angle are symmetrical about the nadir. The latitudedependent deviations of MHS window channel biases are positive and range from 0–7 K. For MHS non-window channels,the latitudinal deviations between measured brightness temperatures and model-simulated brightness temperatures are larger when the detection height is higher. No systematic warm or cold deviations are found in the global spatial distribution of difference between measured brightness temperatures and model-simulated brightness temperatures over oceans after removing scan-angle and latitudinal deviations. The corrected biases of five different MHS channels decrease differently with respect to the increase in IWP. This decrease is stronger when LWP values are higher.  相似文献